WSEAS Transactions on Fluid Mechanics


Print ISSN: 1790-5087
E-ISSN: 2224-347X

Volume 13, 2018

Notice: As of 2014 and for the forthcoming years, the publication frequency/periodicity of WSEAS Journals is adapted to the 'continuously updated' model. What this means is that instead of being separated into issues, new papers will be added on a continuous basis, allowing a more regular flow and shorter publication times. The papers will appear in reverse order, therefore the most recent one will be on top.


Volume 13, 2018



A New Method of One-Pot Synthesis of Efficient Au/SnO2 Electrocatalysts for Fuel Cells

AUTHORS: Agnieszka Martyla, Monika Osinska-Broniarz, Maciej Kopczyk, Bogna Sztorch, Marta Dobrosielska, Robert E. Przekop

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ABSTRACT: Electro-oxidation of methanol in acidic solution was investigated on Au/SnO2 based electrocatalyst obtained by the sol–gel method. Au/SnO2 systems were prepared by one-pot synthesis using a sol–gel method and tin (IV) acetate as a precursor of SnO2 and water solution of HAuCl4 acid as a source of metallic phase. The described method, thanks to its simplicity and mild processing temperature, offers uniform dispersion of metal phase in the bulk of the gel forming as a result of hydrolysis and condensation of tin precursor. It has been found that the obtained system exhibits high electrocatalytic activity.

KEYWORDS: Sol–gel, One-pot method, Electrocatalyst, Fuel Cells

REFERENCES:

[1] F. Samimi, M. R. Rahimpour, Chapter 20 – Methanol Production in Thermally Coupled, Fluidized-Bed, Bubble-Column and Membrane Reactors, Methanol, Science and Engineering, 2018, pp. 381–397.

[2] R. N. Singh, A. Singh and Anindita, Electrocatalytic activity of binary and ternary composite films of Pd, MWCNT, and Ni for ethanol electro-oxidation in alkaline solutions, Carbon, vol. no 34, 2009, pp. 271-278.

[3] C. A. Bessel, K. Laubernds, N. M. Rodriguez and R. T. K. Baker, Characteristics of Copper Particles Supported on Various Types of Graphite Nanofibers, J. Phys. Chem. B, vol no 105, 2001, pp. 1115–1118.

[4] A. Martyla, M. Kopczyk, P. Marciniak, R. Przekop, One-pot method of synthesis of Pt/SnO2 system and its electrocatalytic activity, Chemistry Central Journal, 8:49, 2014, 11 pages.

[5] F. Takasaki, S. Matsuie, Y. Takabatake, X. Noda, A. Hayashi, Y. Shiratori, K. Ito, K. Sasaki, Carbon free Pt electrocatalysts supported SnO2 for polymer electrolyte fuel cells: electrocatalytic activity and durability, J Electrochem Soc, vol. 158, 2011, pp: 1270– 1275

[6] P. Zhang, S. Y. Huang, B. N. Popov, Mesoporous tin oxide as an oxidation-resistant catalyst support for proton exchange membrane fuel cells, J Electrochem Soc, vol no 157, 2010, pp: 1163–1172.

[7] V. Zielasek, B. Jurgens, C. Schulz, J. Biener M. M. Biener, A. V. Hamza, M. Baumer, Gold catalysts: nanoporous gold foams, Angew Chem Int Ed, vol. no 45, 2006, pp: 8241-8244.

[8] M. Ojeda, B. Z. Yhan, E. Iglesia, Mechanistic interpretation of CO oxidation turnover rates on supported Au clusters, J. Catal, vol. no 285, pp: 92-102.

[9] S. E. Davis, B. N. Zope, R. J. Davis, On the mechanism of selective oxidation of 5- hydroxymethylfurfural to 2,5- furandicarboxylic acid over supported Pt and Au catalysts, Green Chem, vol no 14, 2012, pp: 143- 147.

[10] T. Mitsudome, A. Noujima, T. Mizugaki, K. Jitsukawa, K. Kaneda, Supported gold nanoparticles as a reusable catalyst for synthesis of lactones from diols using molecular oxygen as an oxidant under mild conditions, Green Chem., vol. no 11, 2009, pp: 793-797.

[11] Z. Zhang, X. J. Cui, F. Shi, Z. Q. Deng, NanoGold Catalysis in Fine Chemical Synthesis, Chem Rev, vol. no 112, 2011, pp: 2467- 2505.

[12] A. Leyva‐Perez, A. Corma, Similarities and differences between the “relativistic” triad gold, platinum, and mercury in catalysis, Angew Chem, Int Ed, vol. no 51, 2012, pp: 614- 635.

[13] G. Selvarani, S. V. Selvaganesh, S. Krishnamurthy, G. V. M. Kiruthika, P. Sridhar, S. Pitchumani, A. K. Shukla, A MethanolTolerant Carbon-Supported Pt−Au Alloy Cathode Catalyst for Direct Methanol Fuel Cells and Its Evaluation by DFT, J. Phys. Chem. C, vol. no 113, 2009, pp: 7461- 7468.

[14] C. Jeyabharathi, P. Venkateshkumar, J. Mathiyarasu, K. L. N. Phani, Platinum - tin bimetallic nanoparticles for methanol tolerant oxygen-reduction activity, Electrochim. Acta, vol. no 54, 2008, pp: 448-454.

[15] V. Barsykov, V. Khomenko, The influence of polymer binders on the performance of cathodes for lithium-ion batteries, Sci J Riga Tech Univ Mat Sci Appl Chem, vol no 1, 2010, pp: 67-71.

[16] S. Sharma, N. Dhiman, D. Pathak, R. Kumar Effect of nano-size fumed silica on ionic conductivity of PVdF-HFP-based plasticized nano-composite polymer electrolytes, Ionics, vol no 22, 2016, pp: 1865-1872.

[17] K. Otto, I. Oja Acik, M. Krunks, K. Tõnsuaadu, Mere, Thermal decomposition study of HAuCl4·3H2O and AgNO3 as precursors for plasmonic metal nanoparticles, J Therm Anal Calorim, vol no 118, 2014, pp: 1065-1072.

WSEAS Transactions on Fluid Mechanics, ISSN / E-ISSN: 1790-5087 / 2224-347X, Volume 13, 2018, Art. #14, pp. 108-112


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